|
|
acetone_cyanohydrin <=> cyanide + acetone
|
4.1.2.37
hydroxynitrilase
4.1.2.46
aliphatic (R)-hydroxynitrile lyase
4.1.2.47
(S)-hydroxynitrile lyase
|
–
–
–
|
MK
|
| |
BRENDA:
BR368
KEGG:
R01553
MetaCyc:
ACETONE-CYANHYDRIN-LYASE-RXN
SABIO-RK:
1710
|
|
|
|
UDP-glucose + acetone_cyanohydrin <=> H+ + linamarin + UDP
|
2.4.1.63
linamarin synthase
|
–
|
MK
|
| |
BRENDA:
BR44240
KEGG:
R03625
MetaCyc:
LINAMARIN-SYNTHASE-RXN
|
|
|
|
linamarin + H2O <=> acetone_cyanohydrin + D-glucose
|
3.2.1.117
amygdalin beta-glucosidase
3.2.1.21
beta-glucosidase
|
–
–
|
MK
|
| |
BRENDA:
BS361131
KEGG:
R10040
MetaCyc:
RXN-5341
|
|
|
|
(E/Z)-isobutyraldoxime + reduced_flavodoxin + O2 <=> acetone_cyanohydrin + flavin + 2 H2O
|
1.14.14.41
(E)-2-methylbutanal oxime monooxygenase
|
–
|
|
| |
BRENDA:
BR51943
KEGG:
R11598
|
|
|
|
Isobutyronitrile + reduced_flavodoxin + O2 <=> acetone_cyanohydrin + flavin + H2O
|
1.14.14.41
(E)-2-methylbutanal oxime monooxygenase
|
–
|
K
|
| |
BRENDA:
BR51946
KEGG:
R11642
|
|
|
|
Isobutyraldoxime + NADPH + H+ + O2 <=> acetone_cyanohydrin + NADP+ + 2 H2O
|
not assigned
|
–
|
K
|
| |
KEGG:
R10038
|
|
|
|
linustatin + H2O <=> acetone_cyanohydrin + gentiobiose
|
3.2.1
|
–
|
M
|
| |
MetaCyc:
RXN-13646
|
|
|
|
acetone_cyanohydrin + H2O <=> 2-Methyllactate + NH3
|
3.5.5.1
nitrilase
|
–
|
|
| |
MetaCyc:
RXN-17607
|
|
|
|
2-hydroxyisobutyramide <=> acetone_cyanohydrin + H2O
|
4.2.1.84
nitrile hydratase
|
–
|
|
| |
MetaCyc:
RXN-17609
|
|
|
|
(E)-2-methylpropanal-oxime + reduced_[NADPH-hemoprotein_reductase] + O2 <=> acetone_cyanohydrin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.41
(E)-2-methylbutanal oxime monooxygenase
|
–
|
|
| |
MetaCyc:
RXN-18099
|
|
|
|
Isobutyronitrile + O2 + reduced_[NADPH-hemoprotein_reductase] <=> acetone_cyanohydrin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
M
|
| |
MetaCyc:
RXN-5082
|
|
|
|
3,3-dimethyl-2-butanone + acetone_cyanohydrin <=> 2-Hydroxy-2,3,3-trimethylbutyronitrile + acetone
|
4.1.2.46
aliphatic (R)-hydroxynitrile lyase
|
–
|
|
| |
BRENDA:
BS427956
|
|
|
|
acetyltrimethylsilane + acetone_cyanohydrin <=> (R)-2-trimethylsilyl-2-hydroxy-ethylcyanide + acetone
|
4.1.2.46
aliphatic (R)-hydroxynitrile lyase
|
–
|
|
| |
BRENDA:
BS379143
|
|
|
|
acetyltrimethylsilane + acetone_cyanohydrin <=> (S)-2-trimethylsilyl-2-hydroxyl-propionitrile + acetone
|
4.1.2.47
(S)-hydroxynitrile lyase
|
–
|
|
| |
BRENDA:
BS379144
|
|
|
|
3,3-dimethyl-2-butanone + acetone_cyanohydrin <=> (S)-2-hydroxy-2-methyl-3,3-dimethyl-butyronitrile
|
4.1.2.47
(S)-hydroxynitrile lyase
|
–
|
|
| |
BRENDA:
BS379016
|
|
